FEMA 4106
2,5-Dimethylfuran
CAS: 625-86-5
Molecular Formula: C6H8O
FEMA 4106 - Names and Identifiers
| Name | 2,5-Dimethylfuran |
| Synonyms | NSC 6220 AI3-21212 FEMA 4106 CCRIS 3158 DIMETHYL FURAN 2,5diMethylturan 2,5-DIMETHYLFURAN 2,5-Dimethylfuran 2,5-dimethyl-fura Furan, 2,5-dimethyl- |
| CAS | 625-86-5 |
| EINECS | 210-914-3 |
| InChI | InChI=1/C6H8O/c1-5-3-4-6(2)7-5/h3-4H,1-2H3 |
| InChIKey | GSNUFIFRDBKVIE-UHFFFAOYSA-N |
FEMA 4106 - Physico-chemical Properties
| Molecular Formula | C6H8O |
| Molar Mass | 96.13 |
| Density | 0.905g/mLat 20°C |
| Melting Point | -62 °C |
| Boling Point | 92-94°C(lit.) |
| Flash Point | 29°F |
| JECFA Number | 1488 |
| Water Solubility | Slightly miscible with water. Miscible with ethanol and fats. |
| Vapor Presure | 57.1mmHg at 25°C |
| Vapor Density | 3.31 (vs air) |
| Appearance | Liquid |
| Specific Gravity | 0.903 |
| Color | Clear colorless to amber |
| BRN | 106449 |
| Storage Condition | Flammables area |
| Refractive Index | n20/D 1.441(lit.) |
| Use | Used as a pharmaceutical Intermediate |
FEMA 4106 - Risk and Safety
| Risk Codes | R11 - Highly Flammable R22 - Harmful if swallowed R2017/11/22 - |
| Safety Description | 16 - Keep away from sources of ignition. |
| UN IDs | UN 1993 3/PG 2 |
| WGK Germany | 3 |
| RTECS | LU0875000 |
| FLUKA BRAND F CODES | 8 |
| TSCA | Yes |
| HS Code | 29321900 |
| Hazard Note | Harmful/Flammable |
| Hazard Class | 3 |
| Packing Group | II |
FEMA 4106 - Reference Information
| FEMA | 4106 | 2,5-DIMETHYLFURAN |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| biomass fuel | 2,5-dimethylfuran (DMF,2,5-DMF) is a biomass-derived chemical and is the most widely studied fuel alternative. It has many excellent properties similar to gasoline. DMF can be miscible with gasoline or used alone. Compared with biofuel ethanol, which is easily soluble in water, difficult to store and has low combustion performance, DMF is considered as a biomass fuel with more development prospects. |
| application prospect | 2,5-furandicarboxylic acid (FDCA) is one of the 12 "platform compounds" of the U.S. Department of Energy and has broad application prospects. Its structure is similar to that of terephthalic acid, and it is considered to replace terephthalic acid as an important raw material for the manufacture of polyester plastics, and to manufacture a new generation of polyterephthalate-like (PET) biodegradable plastics; Its structure has the characteristics of pentacyclic bifunctional groups. Compared with the six-membered ring structure of terephthalic acid, it has an asymmetric molecular arrangement, so it can also be used to synthesize optical/gas barrier special functional polymer materials; 2,5 furandicarboxylic acid can also be used as an important intermediate for other fine chemicals, drugs and pesticides. Therefore, the preparation of 2, 5-furandicarboxylic acid is considered to be a very representative sustainable biotransformation process to replace petroleum production, with great application prospects and potential. |
| Preparation | At present, DMF is mainly obtained by hydrogenation/hydrogenolysis of 5-hydroxymethylfurfural (HMF) catalyzed by metal catalysts, and most of the catalysts include Palladium, ruthenium and other precious metals. In recent years, there have been some reports on the catalysis of non-precious metals such as nickel, cobalt, copper and iron. 2,5-DMF can also be efficiently produced from fructose in one pot. |
| Use | Used as a pharmaceutical intermediate |
| category | flammable liquid |
| toxicity classification | highly toxic |
| acute toxicity | inhalation-rat LCL0: 500 PPM/ 4 hours |
| flammability hazard characteristics | flammability in case of open flame, high temperature and oxidant; Combustion produces stimulating smoke |
| storage and transportation characteristics | warehouse ventilation and low temperature drying; Store separately from oxidants and acids |
| fire extinguishing agent | dry powder, dry sand, carbon dioxide, foam, 1211 fire extinguishing agent |
Last Update：2024-04-09 02:00:04
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